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Solder Joint Reliability


Solder Joint Reliability of Gold Surface Finishes (ENIG, ENEPIG and DIG) for PWB Assembled with Lead Free SAC Alloy.

By George Milad and Don Gudeczauskas Uyemura International Corp

, Southington CT

As the efforts continue towards meeting RoHS requirements and the elimination of lead by mid 2006 for some countries, finding the ideal surface finish is on most manufacturers’ minds. The surface finish has to be lead free and more important should be able to produce a reliable solder joint when assembled at high temperature with a lead free solder. Presently there are a series of alternate surface finishes in use throughout the printed circuit industry. Some finishes are widely used and others are used for very specific applications. These include: Gold based Finishes:

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Electroless Nickel /Immersion Gold ENIG Electroless Nickel/Electroless Palladium/Immersion Gold ENEPIG Direct Immersion Gold (DIG)

Other Finishes:

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Organic Solderabilty Preservatives OSP Immersion Silver IAg Immersion Tin ISn Selective OSP/ENIG, DIG/ENIG

Most of these finishes have a well documented record of solder joint reliability over time as they have been used for many years

with eutectic Sn/Pb solder. The key question now is the solder joint reliability of these finishes if they are assembled at higher temperatures using lead free alloys. This article will present lead free (SAC 305 alloy) solder joint reliability data with the gold finishes namely ENIG, ENEPIG and DIG. SAC 305 is an alloy composed of Sn with 3.0%Ag and 0.5%Cu. SAC alloy has a melting point temperature of 218°C compared to Sn/Pb at 183°C. Solder balls of SAC alloy and Eutectic Sn/Pb were soldered to BGA pads finished with the different surfaces under investigation. The soldered coupons were then placed in an oven at 150oC from 0 to up to 1000 hours to simulate aging. At different time intervals samples were removed and subjected to ball pull testing. In addition SEM cross sections were also examined.

Sample Preparation for ENIG, ENEPIG and DIG deposition
Sample coupons for evaluation were prepared as follows: copper-clad laminate (FR4), was acid copper plated to 1.0 mil thickness. BGA pads of 0.6 mm diameter were defined with soldermask., using commercially available products. A set of coupons were then plated with each of the following surface finishes. Ni-7%P/Au (ENIG) (5?m/0.05?m), (ENEPIG) (5?m/0.06?m/0.03?m) and DIG (0.04?m).

Evaluation Method of Solder Joint and Results
On the various ENIG and ENEPIG sample substrates, solder balls of Sn/37Pb and Sn/3.0Ag/0.5Cu were mounted, followed by heat treatment at 150oC in air for 0, 100, 300, 500, and 1000 hours to conduct ball pull tests. For the DIG samples only the SAC alloy balls were mounted and ageing was simulated up to 500 hours for ball shear testing and 1000 hours for cross section analysis. The conditions of ball pull tests are shown in Table 1. Table 1. Ball pull test conditions Solder ball 0.76mm, Sn-37Pb Solder (Senjyu)

0.76mm, Sn-3.0Ag-0.5Cu Solder (Senjyu)

Pad Diameter Flux Reflow equipment Ball Pull Ball Pull Speed

0.6mm 529D-1 RMA type (Senjyu) TMR-15-22LH (Tamura) Dage 4000 170?/sec

*Reflow temperature: peak temperature of 240°C Figure 1 Testing Method schematic

Figure 2. Results of ball pull test when Sn/37Pb was used

Figure 3. Results of ball pull test when Sn/3.0Ag/0.5Cu was used

Figure 1 shows a schematic of the experimental sequence. and the results of ball pull tests are shown in Figure 2 (in the case of Sn/Pb solder) and Figure 3 (in the case of Sn/Ag/Cu solder). As shown in Figure 2, in the case of Sn/Pb solder, the change of failure mode which indicates a change of the joint interface showed no clear difference when ENIG film was used, but occurred

remarkably when ENEPIG was used. As shown in Figure 3, when Sn/Ag/Cu solder was used, in contrast, minimum change of failure mode was observed in the case of ENIG film, but no change of failure mode was observed in the case of ENEPIG film, exhibiting excellent characteristics. SEM examination of the different IMCs (intermetallic layers) show that the IMC thickness in general grows over time at elevated temperature. This growth does not impair the solder joint strength of ENIG, ENEPIG or DIG under the conditions of SAC alloy soldering. As shown in Figure 5, eutectic Sn/Pb SEM examination explained why the ENEPIG failed prematurely with aging. There was irregular areas of excessive IMC growth. This is believed to be the result of the incompatibility of Pd and Pb (no IMC formation). In contrast the IMC formed with ENEPIG and SAC alloy had superior strength and limited thickness. It is theorized that the Pd layer minimized/controlled the diffusion of the Ni into the Sn. Figure 6 shows the intermetallics formed after ageing a solder joint with DIG. Figure 4. DIG Ball Pull vs Time

For DIG Figure 4, the failure mode did not exhibit significant loss of strength over 500 hun age simulation.

Figure 5. SEM photographs (1000X)of IMC

Figure 6. EPMA analysis of DIG with SAC alloy soldering 1000 hrs at 150°C

CONCLUSION
Both ENIG and ENEPIG form Ni/Sn intermetallic solder joints with the SAC alloy. DIG on the other hand forms a Cu/Sn intermetallic. ENIG performed very well with both eutectic Sn/Pb and

with SAC alloy. ENEPIG in this investigation proved not to be a suitable finish for eutectic Sn/Pb soldering as was previously believed; it does however produce a superior Ni/Sn solderjoint with SAC alloy DIG performed real well with both eutectic (not included in this study) as well as with lead free SAC alloy. The absence of Ni in the DIG finish renders it unique for applications where Rf signals are propagated and where Ni may cause an interference. Unlike other immersion processes, DIG solder joints are not prone to voiding.


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