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德国拜耳热塑性弹性体TPU-MSDS


。医就即立应,理护当适的肤皮对及伤烫肤皮的起引能可疗治为 。皮结品产的上肤皮在粘去除剂溶用使能不也制强能不既 。却冷水量大用即立 :物熔热触接 肤皮触接若 施措救急 分部四第 酯氨聚塑热 息信成组 分成 分部三第 令指 据根 述概性险危 分部二第
EC 2006/121/EC 1999/45/EC :

。害无境环和康健对品产该,义定的规法家国的生衍

和版编改效有其及



司公限有)国中(技科料材耳拜:称名商货供 司公 产生的品产料塑制模 000000 X543 NAPOMSED
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途用 称名文英中品物 息信品产 识标业企及品学化 分部一第
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EC .

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书明说术技全安品学化

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。去除风排效有过通须必尘粉 。 值限触接所场作工的议建分部 第过超应不)度浓物害有(,施设气排部局或 和风通的好良供提应 。物染污气空的量少出放会下件条理处的议建在 。风排效有供提区作工在须必,时品产本理处工加和 粒颗燥干,器容新启开在如时要必,风通分充要 置处 存储与置处作操 分部七第
: / 13 8

。分部 第见施措弃废它其 议建它其 。理处待以器容的适合入装并洗清 。尘粉成形止防 。备设作操械机用使 法方除清 。统系水污活生或水表地入倒止禁 施措护保境环 。开离员人权授经未令。气排 风通的分充保确 !倒滑心小-粒颗 。)分部 第见(备设护防戴 施措护防人个 施措急应漏泄 分部六第
: : : / 8

。中水表地或水下地,壤土入流水用火灭的染污止禁 。器吸呼式气供自戴佩须必员人防消 。尘烟进吸要不 下况情炸爆或 和火着在 。氢化氰的量痕和物化氧氮、碳化氧二、碳化氧一放释时烧燃 粉干学化 沫泡 水 剂火灭的适合 施措防消 分部五第 。位部染污洗冲底彻皂肥和水的量大用即立,时触接肤皮 。息信下以考参品产该作操下温室
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书明说术技全安品学化
EC 1907/2006/EC

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,

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令指 据根

。罩面 罩眼戴 护防睛眼 。换更须必套手的坏损或 和染污 烯乙氯聚 ;料材适合的套手护防 护防部手 。备设护防吸呼的器滤过粒颗型 带的定规 合符用使,时尘粉生产 护防统系吸呼
CN OEL TWA

尘总 尘总

值限尘粉总 值限尘粉总 喃呋氢四 喃呋氢四 喃呋氢四 喃呋氢四 质物
109-99-9

注备 值阈

值数 型类

( 准基 号摘文学化

。值限极的供提所下以 守遵保确以,施设气换风通的够足供提和给供的气空鲜新效有证保域区的气蒸生产在要验经于基 。规法关有的质物下以守遵要中程过理处温高在是其尤,时品产该工加

度温存储 。燥干与闭密器容持保 存储
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: < 40 °C

/

CAS No.) 109-99-9

EU ELV

TWA

50 ppm 150 mg/m3 100 ppm 300 mg/m3

收吸肤皮由经能可

护防人个 制控露暴 分部八第

令指 据根

/

/

:

:

- PVC (>= 0.5 mm)

:

109-99-9

109-99-9

EN 374-3

EN 143

CN OEL

CN OEL

EU ELV

CN OEL

P1

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STEL

TWA

STEL

STEL

10 mg/m3

450 mg/m3

8 mg/m3

300 mg/m3

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。物合混体气毒有的物化氧氮和碳化氧二、碳化氧一含要主生产会烧燃全完不或烧闷 物产解分险危 。应反害危到察观未 应反害危 性应反和性定稳 分部十第 用适不 用适不
> 210 °C : : :

质性学化理物 分部九第

。物衣的染污被换更 。放存独单服作工将 。脸洗手洗后束结作工和前息休 。草烟和料饮,物食离远 施措生卫 。脂油肤护涂 。气蒸 尘粉入吸止禁 施措护防多更 。服护防的当适着穿 护防体身
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令指 据根

:

味无乎几 粒颗 异而色染据根

限极炸爆 度温燃自 度温燃引 值 性溶水 度粘力动 压气蒸和饱 度密堆 度密 点化软 味气 态形 色颜
pH : : : : : : : : : :



:

:

:

/

:

500 - 700 kg/m3

> 120 °C

1,2 g/cm?

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用适不 溶不乎几 用适不 用适不

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。弃废行进规法地当和家国、际国的用适守遵需必 置处弃废 分部三十第

。解降物生易不品产该 。题问态生无时用使确正在品产该料预,性溶不的中水和度密的它据根 。水于溶不乎几品产本 息信他其的性毒态生关有 。中壤土或水废,道水排入倒止禁 息信学态生 分部二十第 。响影害有无时作操确正在品产该,息信品产和验经的们我据根 :息信加附
109-99-9 R36/37 :

。统系吸呼及睛眼激刺

喃呋氢四 ) 含(类酯酸氰异 质物

。敏过起引可入吸 ( 语短性险危 号摘文学化
CAS No.) R42

。规法关有的质物下以守遵要中程过理处温高在是其尤,时品产该工加 。)现出后滞能可喘哮 ,嗽咳,难困吸呼如状症(大增而高升度浓随度程害危,险风之敏致或 和性激刺致导有露暴度过 。多增著显量气蒸酯酸氰异的生产致导将,度温理处的议建过超 。酯酸氰异的量少放释会,下件条理处的议建在 息信学理毒 分部一十第
: 230 °C

。解分始开时
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解分热
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书明说术技全安品学化
EC 1907/2006/EC

令指 据根

NCO

-

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。明指别特非除,用适不合结的程过何任与或合混的质物它其与品产本于对,品产的定指于 用 适仅息信此。标指量质或保担是为认被能不而,导指的等弃废和输运、存储、理处、用使、作操全 安为 作仅息信的出给所,的确正是日之布发其在息信的供提书明说术技全安此,息信和识知的们我据根 息信充补 息信它其 分部六十第 令指 据根 息信规法 分部五十第
EC 2006/121/EC 1999/45/EC

。签标害危贴加需无,规法家国的生衍和版编改效有其及

息信输运 分部四十第
选有型类的身本料材据依有唯。品产制模的新成工加再,融熔再被可,后理处当适过经。用利再收回合适品产本 。收回行进规法关相境环和令法家国照按应器容 点集收的当适往送案方收回的存现业工学化据根可,) 干滴 至直干排或擦刮,倒倾经如例(空倒器容将能可尽
EWC

。规法当适的)
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(类分物弃废洲欧据根应,弃废内域领盟欧在
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令指 据根

IMDG

IATA

ADNR

ADR/RID

--

--

--

--

:

。放存开分 物食与应 。燥干持保 。味有微 。物货 险危非

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息信它其

SAFETY DATA SHEET according to EC directive 2001/58/EC
Version 1.0 Revision Date 07.05.2007

<####>112000021632
Print Date 08.05.2007>

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product information Trade name : DESMOPAN 345X

2. COMPOSITION/INFORMATION ON INGREDIENTS Thermoplastic polyurethane

3. HAZARDS IDENTIFICATION Not a product dangerous for health or the environment according to the definition of EC Directives 67/548/EEC or 1999/45/EC and their valid adaptations and derived national regulations.

4. FIRST AID MEASURES In case of skin contact: CONTACT WITH THE HOT MELT: Cool immediately with plenty of water. Do not remove product crusts which may have formed neither forcibly nor by applying any solvents to the skin involved. To obtain treatment for possible burns, and appropriate skin care, seek medical advice immediately. The following information refers to the handling of the product at room temperature. In case of skin contact wash affected areas thoroughly with soap and plenty of water.

5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Water, Foam, Dry chemical Burning releases carbon monoxide, carbon dioxide, oxides of nitrogen and traces of hydrogen cyanide. In the event of fire and/or explosion do not breathe fumes.

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BMS_SDS_DE / DE

SAFETY DATA SHEET according to EC directive 2001/58/EC

<#####>112000021632
Print Date 08.05.2007>

DESMOPAN 345X
Version 1.0 Revision Date 07.05.2007

Firemen must wear self-contained breathing apparatus. Do not allow contaminated extinguishing water to enter the soil, ground-water or surface waters.

6. ACCIDENTAL RELEASE MEASURES Personal precautions: Put on protective equipment (see chapter 8). Granules - slip hazard! Ensure adequate ventilation/exhaust extraction. Keep unauthorized persons away. Environmental precautions: Do not flush into surface water or sanitary sewer system. Methods for cleaning up: Use mechanical handling equipment. Avoid dust formation. Sweep up and shovel into suitable containers for disposal. Additional advice: For further disposal measures see chapter 13.

7. HANDLING AND STORAGE Handling Adequate ventilation and if necessary, effective exhaust must be provided at the workplace when opening fresh drums, drying granules and processing the material. Under recommended processing conditions small amounts of emissions may occur. Provided good ventilation and/or local exhaust systems are used, the Workplace Exposure Limit(s) stated in Chapter 8 should not be exceeded. Dust must be removed by effective exhaust ventilation. Storage Keep container tightly closed and dry. VCI storage class (VCI = German Association of the Chemical Industry): 11 Storage temperature: < 40 °C

8. EXPOSURE CONTROLS / PERSONAL PROTECTION The regulations for the substances listed below must be observed when processing this product, particularly if processing takes place at elevated temperatures. In our experience the provision of effective fresh-air and exhaust ventilation equipment at the points where vapors may be generated will ensure compliance with the tolerance limits quoted below.

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BMS_SDS_DE / DE

SAFETY DATA SHEET according to EC directive 2001/58/EC

<#####>112000021632
Print Date 08.05.2007>

DESMOPAN 345X
Version 1.0 Revision Date 07.05.2007

Substance

CAS-No.

Basis

Type

Value

tetrahydrofuran

109-99-9

TRGS 900

50 ppm 150 mg/m3

tetrahydrofuran tetrahydrofuran

109-99-9 109-99-9

TRGS 900 TRGS 900 STEL CL

Ceiling Remarks Limit Value 2 If in compliance with the OEL and BEL values, then there should be no risk of reproductive damage. Dermal absorption possible Category I: substances for which the localized effect has an assigned OEL respiratory passages.

tetrahydrofuran

109-99-9

EU ELV

TWA

tetrahydrofuran

109-99-9

EU ELV

STEL

50 ppm 150 mg/m3 100 ppm 300 mg/m3 Dermal absorption possible inhalable fraction measured as the alveolar aerosol content Category II: substances with a resorptive effect.

tetrahydrofuran General limiting value of dust General limiting value of dust General limiting value of dust

109-99-9

EU ELV TRGS 900 10 mg/m3 TRGS 900 3 mg/m3 TRGS 900 STEL CL 2 2

Respiratory protection: In case of dust formation use respiratory equipment with filter type particle filter P1 according to EN 143. Hand protection: Suitable materials for safety gloves; DIN EN 374-3: polyvinyl chloride - PVC (>= 0.5 mm) Contaminated and/or damaged gloves must be changed. Eye protection: Wear eye/face protection. Skin and body protection: Wear suitable protective clothing. Further protective measures: Do not breathe dust/vapor. Grease skin. Hygiene measures: Keep away from foodstuffs, drinks and tobacco. Wash hands and face before breaks and at the end of work. Keep working clothes separately. Change contaminated clothing.

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BMS_SDS_DE / DE

SAFETY DATA SHEET according to EC directive 2001/58/EC

<#####>112000021632
Print Date 08.05.2007>

DESMOPAN 345X
Version 1.0 Revision Date 07.05.2007

9. PHYSICAL AND CHEMICAL PROPERTIES Colour: Form: Odour: Softening point: Density: Bulk density: Vapour pressure: Viscosity, dynamic: Water solubility: pH: Ignition temperature: Autoignition temperature: Explosion limits: different according to colouration granular almost odourless > 120 °C ca. 1,2 g/cm? 500 - 700 kg/m3 not applicable not applicable practically insoluble not applicable > 210 °C not applicable not applicable

10. STABILITY AND REACTIVITY Hazardous reactions: No hazardous reactions observed. Hazardous decomposition products: Smouldering or incomplete combustion leads to the formation of toxic gas mixtures consisting mainly of CO, CO2 and nitrogen oxides. Thermal decomposition: Decomposition begins at 230 °C.

11. TOXICOLOGICAL INFORMATION Under recommended processing conditions small amounts of isocyanates may be emitted. Exceeding the recommended processing temperatures leads to a significant increase in the amount of isocyanate vapor generated. Over-exposure entails a risk of concentration-dependent inhalatory irritation and/or sensitization by isocyanates (delayed appearance of difficult breathing, coughing, asthma is possible). The regulations for the substances listed below must be observed when processing this product, particularly if processing takes place at elevated temperatures.

Substance Isocyanates (all, as NCO) tetrahydrofuran

CAS-No.

R-phrase(s) R42 May cause sensitisation by inhalation. R36/37 Irritating to eyes and respiratory system.

109-99-9

Additional information: According to our experience and information the product has no harmful effects on health if properly handled.

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SAFETY DATA SHEET according to EC directive 2001/58/EC

<#####>112000021632
Print Date 08.05.2007>

DESMOPAN 345X
Version 1.0 Revision Date 07.05.2007

12. ECOLOGICAL INFORMATION Do not allow to escape into waterways, wastewater or soil. Further information on ecology: The product is practically insoluble in water. In view of its consistency and insolubility in water, no ecological problems are to be expected if the product is properly handled. The product is not readily biodegradable.

13. DISPOSAL CONSIDERATIONS Dispose in accordance with applicable international, national and local laws, ordinances and statutes. For disposal within the EC, the appropriate code according to the European Waste Catalogue (EWC) should be used. After containers have been emptied as thoroughly as possible (e.g. by pouring, scraping or draining until "drip-dry"), they can be sent to an appropriate collection point set up within the framework of the existing take-back scheme of the chemical industry. Containers must be recycled in compliance with national legislation and environmental regulations. The product is suitable for mechanical recycling. After appropriate treatment it can be remelted and reprocessed into new moulded articles.Mechanical recycling is only possible if the material has been selectively retrieved and carefully segregated according to type.

14. TRANSPORT INFORMATION ADR/RID ADNR IATA IMDG ----: Not dangerous cargo. Slight smell. Keep dry. Keep separated from foodstuffs.

Other information

15. REGULATORY INFORMATION No labeling necessary according to EC Directives 67/548/EEC or 1999/45/EC and their valid adaptations and derived national regulations. National legislation

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SAFETY DATA SHEET according to EC directive 2001/58/EC

<#####>112000021632
Print Date 08.05.2007>

DESMOPAN 345X
Version 1.0 Revision Date 07.05.2007

Water contaminating class (Germany): nw not water endangering (in accordance with Annex 1 to the Directive on Water-Hazardous Substances)

16. OTHER INFORMATION Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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BMS_SDS_DE / DE

Safety Data Sheet
Date of issue: June 28, 2004 *1. Identification of the substance/preparation and the company DESMOPAN 345 Application: Production of molded plastic articles Bayer MaterialScience AG, HSEQ?PRC (Product Safety)

076892/06
Page 01 of 05

2.

Composition/information on ingredients Thermoplastic polyurethane Hazards identification Not a product dangerous for health or the environment according to the defidefinition of EC Directives 67/548/EEC or 1999/45/EC and their valid adaptations and derived national regulations. First?aid measures CONTACT WITH THE HOT MELT: Cooling immediately with plenty of water. Do not remove product crusts which may have formed neither forcibly nor by applying any solvents to the skin involved. In order to obtain medical care for possible burns and for a smooth clean? sing of the skin, seek medical advice immediately. Fire?fighting measures Extinguishing media: water, foam, dry powder. In case of fire or smouldering fire wear respiratory protection equipment.

*3.

*4.

5.

*6.

Accidental release measures granules: slip hazard! Take up mechanically; avoid dust formation. Sweep up and dispose of, if appropriate together with other combustible waste material. For further disposal measures see chapter 13. Handling and storage Handling: Adequate ventilation and if necessary, effective exhaust must be providid at the workplace when opening fresh drums, drying granules and processing the material Under recommended processing conditions small amounts of emissions may occur. Provided good ventilation and/or local exhaust systems are available, the limit values cited under pt. 8 should not be exceeded. Dust must be removed by effective exhaust ventilation. Storage: Protect from moisture and do not expose to temperatures above 40 °C. Keep container tightly closed. (to be continued)

*7.

in accordance with the EU Directives

(gb) DPSTA

Safety Data Sheet
Date of issue: June 28, 2004 DESMOPAN 345 *7.

076892/06
Page 02 of 05

Handling and storage (Continuation) VCI storage class: 11 (VCI: German Association of Chemical Industry) Exposure controls/Personal protection The regulations for the substances listed below must be observed when pro? cessing this product, particularly if processing takes place at elevated temperatures. In our experience the provision of effective fresh?air and exhaust ventilation equipment at the points where vapors may be generated will ensure compliance with the tolerance limits quoted below. Substance CAS?No. R?phrases 1) Classification 2) acc. to ??????????????????????????????????????????????????????????????????????????? isocyanates (?NCO) ? R42 3) ?? ?? diisopropyl?phenylisocyanate 28178?42?9 R22?43 3) ?? ?? tetrahydrofuran 109?99?9 R36/37 ?? 1) Health R?Phrases (Text in Chapter 16) 3) Recommendation TRGS: German Technical Regulations on Dangerous Substances Occupational Exposure Limits (mg/m?), Time Weighted Average: EU U. Kingdom R. of Ireland ACGIH ??????????????????????????????????????????????????????????????????????????? isocyanates (?NCO) ? 0,02 0,02 ? diisopropyl?phenylisocyanate ? ? ? ? tetrahydrofuran 150 150 118 600 fine dust 1) respirable ? 5 4 3 inhalable ? 10 10 10 1) in consequence with mechanical treatment, e.g. grinding, occurring. ACGIH: American Conference of Governmental Industrial Hygienists Respiratory protection: In case of dust formation use respiratory equipment with filter type particle filter P1 according to DIN EN 143. Hand protection: Protective gloves of leather, contaminated or damaged gloves should be replaced. Eye protection: Protective goggles with side shield or tightly fitting protective goggles Body protection: Skin covering working clothes; wear dust?proof overalls if large quantities of dust are generated.

*8.

(to be continued) in accordance with the EU Directives (gb) DPSTA

Safety Data Sheet
Date of issue: June 28, 2004 DESMOPAN 345 *8. Exposure controls/Personal protection (Continuation) Protection and hygienic measures: Avoid inhaling vapours. Avoid inhaling dust. Grease skin. At the end of work, wash hands and face. When using do not eat, drink or smoke. 9.

076892/06
Page 03 of 05

Physical and chemical properties tested in accordance with Form: granules Colour: pale coloured, transparent?opaque Odour: nearly odourless Softening point: 170?200 °C Processing temperature: 190?210 °C Density: 1,23 g/cm? Bulk density: 650?750 kg/m? Vapour pressure: not applicable Viscosity: not applicable Solubility in water: insoluble pH value: not applicable Flash?ignition temperature: > 210 °C Self?ignition temperature: not applicable Explosive limits: not applicable

*10. Stability and reactivity Thermal decomposition: Decomposition begins at 230 °C. Fumes evolved by overheating during improperly processing or by burning may be injurious to health.

Hazardous decomposition products: Smouldering or incomplete combustion leads to the formation of toxic gas mixtures consisting mainly of CO, CO2 and nitrogen oxides; amines, nitriles, aliphatic and aromatic hydrocarbons, aldehydes, ketones, acids, hydrogen cyanide and isocyanates are also formed. Hazardous reactions: No hazardous reactions observed.

in accordance with the EU Directives

(gb) DPSTA

Safety Data Sheet
Date of issue: June 28, 2004 DESMOPAN 345

076892/06
Page 04 of 05

*11. Toxicological information Small quantities of isocyanates, mainly diisopropyl?phenylisocyanate may be released when drums are opened for the first time and when the product is exposed to elevated temperatures (e.g. during drying or processing). Exceeding the recommended processing temperatures leads to a significant increase in the amount of isocyanate vapour generated. Over?exposure entails a risk of concentration?dependent inhalatory irrita? tion and/or sensitization by isocyanates (delayed appearance of difficult breathing, coughing, asthma is possible). Hypersensitive persons may suffer from these effects even at low isocyanate concentrations. According to our experience and information the product has no harmful effects on health if properly handled. *12. Ecological information The product is practically insoluble in water. In view of its consistency and insolubility in water, no ecological problems are to be expected if the product is properly handled. This product is not readily biodegradable. *13. Disposal considerations The product is suitable for mechanical recycling. After appropriate treat? ment it can be remelted and reprocessed into new moulded articles. Mechanical recycling is only possible if the material has been selectively retrieved and carefully segregated according to type. May only be transported to suitable incinerator with reduced non?air emis? sions observing local official regulations. May be disposed of together with household refuse if local official regulations are observed. European Waste Catalogue (EWC) code: 070213 *14. Transport information GGVSE: ?? UN: NODG PG: ?? RID/ADR: ?? UN: NODG PG: ?? ADNR: ?? UN: NODG PG: ?? GGVSee/IMDG Code: ?? UN: NODG PG: ?? MPO: ?? ICAO?TI/IATA?DGR: ?? UN: NRES PG: ?? Declaration for land shipment: ?? Declaration for sea shipment: ?? Declaration for shipment by air: ?? Other information: Not dangerous cargo. Slightly smelling. Keep dry. Avoid heat above +50 °C. Keep separated from foodstuffs. *15. Regulatory information No labeling necessary according to EC Directives 67/548/EEC or 1999/45/EC and their valid adaptations and derived national regulations. Water pollution class (WGK: Not hazardous to water (VwVwS appendix 1) (VwVwS = German Regulation on Substances Hazardous to Water) Swiss law of poison: class of poison ?? ; BAG?T?No. ??.

in accordance with the EU Directives

(gb) DPSTA

Safety Data Sheet
Date of issue: June 28, 2004 DESMOPAN 345 *16. Other information The safety data sheet is also valid for: DESMOPAN VP KU2?8702 DESMOPAN DP 1692A

076892/06
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The following R?Phrases refer to substances that are either contained in this product or may be generated or released during processing, and do not necessarily correspond to the product labeling. Information on labeling the product put into circulation in accordance with EC Directives is given in Chapter 15. Text of all R phrases referred to in sections 2, 3, 8 or 15: R 22: Harmful if swallowed. R 36/37: Irritating to eyes and respiratory system. R 42: May cause sensitization by inhalation. R 42/43: May cause sensitization by inhalation and skin contact. R 43: May cause sensitization by skin contact.

All chapters in the SDS which have been changed since last edition are marked with an asterisk in front of the Chapter number. The data given here is based on current knowledge and experience. The purpose of this Safety Data Sheet is to describe the products in terms of their safety requirements. The above details do not imply any guarantee concerning composition, properties or performance.


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