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New BYK additives CN 2012


New Coating Additives 2011-2012
2011-2012新产品介绍

János Hajas, BYK 8/6/2012

BYK-4511Polymeric Adhesion Promoter for Solvent-free, High Solids and Solvent-borne 2-pack

Epoxy Systems
无溶剂、高固体份和溶剂型双组份环氧体系用聚合物型附着力促进剂

Structure and Working Mechanism of BYK-4511 BYK-4511的结构和作用机理
Epoxy matrix 环氧基料

metal substrate 金属基材

Segments of reactive groups are separated by polymeric backbone 聚合物主链将含反应基团的链段阻隔开
Page 3, Improving Performance of Heavy Duty Coatings

highly surface reactive group 高活性表面反应基团 binder reactive groups 基料反应基团 polymeric backbone 聚合物主链

BYK-4511 Excellent Salt Spray Performance (168 h) 优异的耐盐雾性能

Control 空白

Reference-1 对比-1

Reference-2 对比-2

BYK-4511

Test System: 828 type epoxy / polyamide primer system Additive Dosage: 1 % active substance Substrate: cold rolled smooth steel

测试体系: 828 环氧 / 聚酰胺底漆 助剂用量: 1 % 活性物质 基材: 光亮冷轧卷钢

Page 5, Improving Performance of Heavy Duty Coatings

BYK-4511 Excellent Continuous Condensation Test Results (168 h) 优异的连续凝露试验结果

Control
空白

Reference-1
对比-1

Reference-2
对比-2

BYK-4511

Test System: 828 type epoxy / polyamide primer system Additive Dosage: 1 % active substance Substrate: cold rolled smooth steel
Page 6, Improving Performance of Heavy Duty Coatings

测试体系: 828 环氧 / 聚酰胺底漆 助剂用量: 1 % 活性物质 基材: 光亮冷轧卷钢

BYK-4511 Summary 总结

? improves adhesion on several (metal) substrates as sand-blasted steel, cold rolled steel, galvanized steel, aluminum, glass… 改善在多种 (金属) 底材的附着力,如喷砂钢材、光亮冷轧卷钢、镀锌钢材、铝材、玻 璃… ? improves the surface tolerance, e.g. when the paint is applied on oily or corroded surfaces 提高底材容忍度,例如当涂料在油污或是锈蚀表面施工时 ? improves the overall performance of multi-layer systems 改善多涂层体系的整体性能 ? increases the flexibility of the paint film 增加漆膜的柔韧性 ? increases anti-corrosive performance 增加防腐性能

? suitable for baking enamels 适合烘烤体系
? good storage stability in paint formulation 在涂料配方中良好的贮存稳定性 ? no negative influence on gloss, haze, pendulum hardness or cross linking 对光泽、雾影、摆杆硬度或交联反应没有负面影响
Page 7, Improving Performance of Heavy Duty Coatings

DISPERBYK-2155 100% Solids Liquid Wetting and Dispersing Additive
DISPERBYK-2155 100%固体份液态润湿分散剂

DISPERBYK-2155: Spherical Structure Generates Flowable High Molecular Weight Polymer 球形结构可得到易流动的高分子量聚合物

Conventional linear structure: 常规线型结构: MW: Solids content: Viscosity: 20.000 g/mol 100% Not flowable

DISPERBYK-2155 spherical structure: DISPERBYK-2155 球形结构: MW: Solids content: Viscosity: 20.000 g/mol 100% 13.000 mPa.s

8/6/2012, Page 9, Forename Surname, Company or Department, Title of the Presentation

DISPERBYK-2155: Product Profile 产品介绍

Solids content 固含量: Solvent 溶剂:

100% -

Amine value 胺值:
Flash point 闪点: MW 分子量:

48 mg KOH/g
>110°C (230°F) ~ 20.000

8/6/2012, Page 10, Forename Surname, Company or Department, Title of the Presentation

DISPERBYK-2155 in General Industrial Coatings Additive selection chart: Resin-containing pigment concentrates 在一般工业涂料中助剂选择图:含树脂的颜料浓缩浆

Non-polar

Alkyds
Medium-oil Short-oil

Baking Systems

2-pack/NCO

Polar

Long-oil

DISPERBYK-162 DISPERBYK-161
Odor

DISPERBYK-115

DISPERBYK-2163/DISPERBYK-2164
Odor, drying

DISPERBYK-2150 DISPERBYK-2155 DISPERBYK-2025

Odor

8/6/2012, Page 11, Forename Surname, Company or Department, Title of the Presentation

DISPERBYK-2151Hyperbranched Wetting and Dispersing Additive for Epoxy and other Reactive Systems
环氧和其它反应型体系用高度枝化结构的润湿分散剂

Storage Stability of Pigment Concentrates in Epoxy Resin 在环氧颜料浆中贮存稳定
Pigment concentrates based on Araldite GY 793基于Araldite GY 793 的颜料浓缩浆

With polyurethane type W&D additive 聚氨酯类润湿分散剂

With DISPERBYK-2151
Storage after 4 weeks at 50°C

50°C (104°F) 贮存4周

DISPERBYK-2151: A Hyperbranched Aminic Polymer for Epoxy Systems DISPERBYK-2151:适合环氧体系的高度枝化结构的胺类聚合物

Steric hindrance by the polyester chains prevents a reaction between epoxy groups and the aminic pigment affinic surface 聚酯链阻碍了环氧基团与胺锚定基团的反应 ?Polyester side chains are compressed while still encapsulating the aminic groups 聚酯侧链被压缩,胺基依然保持被包裹状态

DISPERBYK-2151: Chemical Composition 化学组成

? Chemical structure 化学结构: ? Solids 固体份: ? Solvent 溶剂:

OH-functional polyester 羟基聚酯 80 % PM acetate 丙二醇甲醚醋酸酯

8/6/2012, Page 15, Forename Surname, Company or Department, Title of the Presentation

Pigments Ground in Various Resin Systems 不同树脂体系的颜料浆
Performance of pigment concentrates based on Aldehyde resin
基于醛基树脂的颜料浓缩浆的性能
Acrylic-Melamine 丙烯酸-三聚氰胺 Alkyd-Melamine 醇酸-三聚氰胺 Polyester-Melamine 聚酯-三聚氰胺 2-pack Epoxy 双组份环氧 TPA /CAB Short-oil Alkyd 短油醇酸 Medium-oil Alkyd 中油醇酸 Long-oil Alkyd 长油醇酸 2-pack Acrylic** 双组份丙烯酸 2-pack Polyester 双组份聚酯 CAB NC (alcohol)

TPA (ketone)

Lower polar TPA* 低极性热塑性丙烯酸

NC (esters) Acid catalyzed Acrylic 酸催化丙烯酸 Acid catalyzed short-oil Alkyd 酸催化短油醇酸

Lower 低
= excellent performance 性能优异

Polarity 极性

Higher 高

* Requires polarity adjustment with 1-2 % BYK-9076 into clear. ** Requires polarity adjustment with 2% DISPERBYK-182 into clear

8/6/2012, Page 16, Forename Surname, Company or Department, Title of the Presentation

DISPERBYK-2151: Areas of Usage 应用领域

Industrial Coatings 工业涂料

Wood Coatings 木器涂料

Protective Automotive Coatings Coatings 汽车涂料 防腐涂料

Ambient Curing Systems 室温固化 体系

Recommended 推荐
Suitable 适用

8/6/2012, Page 17, Forename Surname, Company or Department, Title of the Presentation

Summary: DISPERBYK-2151 总结
? Excellent wetting and dispersing additive (not only) for Epoxy systems
环氧体系用优异的润湿分散剂,也适用其它体系

? In Epoxy coatings it provides 在环氧体系中提供以下性能
o o Long-term storage stability (no gelling) 长期贮存稳定性(不凝胶) Strong viscosity reduction even in 100% systems 显著降低粘度,即使是100%固含体系

? High molecular weight product 高分子量助剂
o Excellent results in numerous resin systems 在多种体系中具有良好的性能表现

? No negative impact on other paint properties 对涂料的其它性能无负面影响

8/6/2012, Page 18, Forename Surname, Company or Department, Title of the Presentation

Starting Point Formulations 起始配方

Solvent-borne Epoxy with DISPERBYK-2151 溶剂型环氧
Kronos 2360 *3 Colour Index Epikote 1001 (75% in Xylene) MPA PM DISPERBYK-2151 (80% solids) BYK-SYNERGIST 2100 BYK-SYNERGIST 2105 Aerosil R 972 Pigment
*2 *1

Bayferrox 3920 *4 PY 42 18,30 20,80

Hostaperm yellow H4G *5 PY 154 16,00 44,40

Novoperm orange HL 70 *5 PO 36 16,00 46,00

Bayferrox 120M *4 PR 101 17,80 15,50

Novoperm red F3RK70 *5 PR 170 20,00 39,95

Hostaperm pink E *5 PR 122 16,00 59,80

Hostaperm violet RL-NF *5 PV 23 28,00 54,40

Heliogen blue L7101F *6 PB 15:4 24,00 50,20

Heliogen green L8735 *6 PG 7 29,60 36,20

Spezial black 4 *2 PB 7 36,70 15,90 15,90

Raven 14 */ PB 7 36,70 15,90 15,90 9,50

PW 6 17,80 19,50

1,90

5,10

9,30

7,40

5,90

9,30

6,20

5,60

7,80

10,00 1,20

9,54

0,60 0,80 60,00 100,00 0,80 55,00 100,00 0,30 30,00 100,00 30,00 100,00 0,80 60,00 100,00

0,75

30,00 100,00

18,00 100,00

12,00 100,00

18,00 100,00

23,00 100,00

22,00 100,00

22,00 100,00

% DISPERBYK-2151 s.o.p. % BYK-SYNERGIST 2100 s.o.p. % BYK-SYNERGIST 2105 s.o.p.

2,5

7,5

27,0

20,0

8,0

25,0

28,0

38,0

35,0

35,0 5,0

35,0

35,0

2,0

2,5

Producer: *1 Momentive Specialty Chewmicals *2 Orion Engineered Carbons *3 Kronos *4 Lanxess *5 Clariant *6 BASF *7 Columbian

8/6/2012, Page 19, Forename Surname, Company or Department, Title of the Presentation

Starting Point Formulations 起始配方

Solvent-free Epoxy with DISPERBYK-2151 无溶剂环氧
Kronos 2360 *3 Colour Index Araldite GY 793
*1

Bayferrox 3920 *4 PY 42 41,77 4,93

Hostaperm yellow H3G
*5

Bayferrox 120M *4 PR 101 33,75 5,95

Novoperm red F3RK70
*5

Hostaperm pink E *5 PR 122 75,75 6,25

Chrome green GN-M
*4

Heliogen blue L7101F
*6

Heliogen green L8735
*6

Special black 4 *2 PB 9 72,57 7,43

PW 6 37,84 1,86

PY 154 59,66 10,04

PR 170 60,71 9,29

PG17 36,97 5,03

PB 15:4 73,89 7,81 0,30

PG 7 66,12 9,98 0,90

DISPERBYK-2151 (80% solids) BYK-SYNERGIST 2100 Aerosil R 972 Pigment
*2

0,30 60,00 100,00

0,30 53,00 100,00

0,30 30,00 100,00

0,30 60,00 100,00 30,00 100,00 18,00 100,00 58,00 100,00 18,00 100,00 23,00 100,00 20,00 100,00

% DISPERBYK-2151 s.o.p.

2,5

7,5

27,0

8,0

25,0

28,0

7,0

35,0

35,0

30,0

% BYK-SYNERGIST 2100 s.o.p.

5,0

Producer: *1 Huntsman *2 Orion Engineered Carbons *3 Kronos *4 Lanxess *5 Clariant *6 BASF

8/6/2012, Page 20, Forename Surname, Company or Department, Title of the Presentation

Starting Point Formulations 起始配方

Aldehyde Resin with DISPERBYK-2151 醛基树脂
Kronos 2360 *3 Bayferrox 120M *4 Novoperm red F3RK70 *5 Hostaperm pink E *5 Hostaperm violet RL-NF *5 PV 23 36,0 46,3 5,7 Heliogen green L8735 *6 PG 7 42,0 23,8 10,1 1,2 1,0 0,4 65,0 100,0 0,8 60,0 100,0 40,0 100,0 18,0 100,0 12,0 100,0 23,0 100,0 18,0 100,0 22,0 100,0 Heliogen blue L7101F
*6

Special black 4 *2

Colour Index Aldehyde Resin (60% solids in PMA) PMA DISPERBYK-2151 ( 80% solids) BYK-SYNERGIST 2100 BYK-SYNERGIST 2105 Aerosil R 972 Pigment
*2

PW 6 20,0 12,6 2,0

PR 101 25,0 6,7 7,5

PR 254 33,5 11,5 14,0

PR 122 20,0 53,5 8,6

PB 15:4 30,0 43,8 7,9 0,3

PBl 7 52,1 16,3 9,6

% DISPERBYK-2151 s.o.p.

2,5

8,0

35,0

38,0

38,0

35,0

35,0

35,0

% BYK-SYNERGIST 2100 s.o.p.

5,0

1,5

% BYK-SYNERGIST 2105 s.o.p.

1,5

Producer: *2 Orion Engineered Carbons *3 Kronos *4 Lanxess *5 Clariant *6 BASF

8/6/2012, Page 21, Forename Surname, Company or Department, Title of the Presentation

BYK-399 Silicone-Free Polymeric Leveling Additive
不含有机硅的聚合物型流平剂

BYK-399 – Polymeric Leveling Additive 聚合物型流平剂 Working Mechanism 作用机理

? Equilizes surface tension differences due to excellent orientation at the paint surface
?由于在涂料优异的定向性,可以使表面张力趋于一致

? Effective at low dosages (depends on system)
低添加量时依然可发挥作用(取决于体系)

Alkyl modification 烷基改性 Polymer backbone 聚合物主链

BYK-399 Recommended Additive Dosage 推荐助剂用量
Recommended additive dosage (depends on system):
推荐助剂用量(取决于体系)

0.05 – 1 % as supplied on total formulation
0.05 – 1 % 供应形式基于总配方

Leveling 流平: Defoaming 消泡:

effective at low dosages 低添加量即有效 higher dosage required (0.7% and higher)
需要相对高的用量(0.7% 或更高)

The additive can be post-added and should be incorporated with medium shear force. 该助剂可以后添加,需要中等剪切力下添加。

BYK-399 in Coil Coatings 卷材涂料 Leveling in a Polyester-Melamine System 聚酯-三聚氰胺体系中的流平
Very clear image 影像非常清晰

0.5% BYK-350

0.5% BYK-399

Polyester System 聚酯体系: Dynapol LH 830 (Evonik) Additive dosage 助剂用量: solid on total formultion 固体成份基于总配方

BYK-399 Key Properties in General Industrial Coatings 在一般工业涂料中的关键性能
? Excellent leveling results and high DOI values
具有优异的流平效果和高 DOI 值

?
?

Suitable for multi-layer systems – very good recoatability
适合多涂层体系 – 良好的重涂性

Silicone-free – no risk of foam stabilization (e.g. airless application)
不含有机硅 – 无稳泡风险(如,无气喷涂)

?
?

Recommended for formulations where silicones can not be used
在不能使用有机硅的情况下,推荐使用该助剂

Leveling additive in combination with silicones
可与有机硅搭配使用的流平剂

DISPERBYK-2022 Wetting & Dispersing Additive for Solvent-Borne Coatings and Pigment Concentrates with Excellent Adhesion “Direct-to-Metal”
用于溶剂型涂料及颜料浓缩浆的不含异氰酸酯的润湿分散剂对金属底材 上有极佳的附着力

DISPERBYK-2022: Product Profile产品概况

Chemistry 化学结构: Solids content 固含量: Solvent 溶剂:

CPT-based structured acrylate co-polymer
基于CPT技术的结构型丙烯酸酯类共聚物

60% Methoxypropylacetate (PMA)

Amine value 胺值:

61 mg KOH/g

Pigment Stabilization in TPA with DISPERBYK-2022 DISPERBYK-2022在TPA体系中的颜料稳定性
Bayferrox yellow 3920

Bayferrox red 130M

No additive

13%* DISPERBYK-2022

No additive

16,5%* DISPERBYK-2022

System: TPA (Paraloid B66) Bayferrox is a trademark of Lanxess Paraloid is a trademark of Rohm & Haas

* additive

as delivered on pigment

Adhesion Test Results 附着力测试
“Direct-to-metal“ applications 直接涂装在金属底材的应用

Additive 1 (basic碱性)

Additive 2 (acidic酸性)

2.5%* DISPERBYK-2022

Typical impact of wetting & dispersing additive 润湿分散剂的典型影响
Alkyd/Melamine baking enamel direct to cold rolled steel

* Additive as supplied on resin solids助剂供应型式对固体树脂计

醇酸氨基体系烤漆直接辊涂在冷轧卷钢上

DISPERBYK-2022: Summary DISPERBYK-2022:总结
? Isocyanate-free widely compatible product from long-oil Alkyd to 2-Pack PU
不含异氰酸酯具从长油醇酸至双组份聚氨酯都有广泛相容性的产品

o Strengths in TPA, TPA/CAB and NC-combi Millbase formulation with and without resin 有树脂或无树脂研磨 o Adjustment of millbase viscosity by decreasing of resin amount in grinding
在研磨阶段降低研磨树脂用量来调节研磨浆粘度

? For single and co-grinds 共研磨和分色研磨 ? Excellent adhesion “direct-to-metal”优秀的金属底材附着性

o Positive impact on salt spray resistance (due to improved adhesion)
由于附着力的提高所以对耐盐雾性能有所提高

BYK-1794 Emission and Silicone-free Polymeric Defoamer for Solvent-free, Solvent-borne, High-solid and UV-Systems
用于无溶剂、溶剂型、高固体份和 UV 体系的零释放、不含有机硅的 聚合物型消泡剂

BYK-1794 Your Benefits 特性与优点

? 100 % solids 100% 固体份 - Emission-free 零释放 - Meets AgBB standard as well as Swiss and French regulations 符合 AgBB(德国)标准以及瑞士、法国相关法规 - VOC-free 不含 VOC ? Suitable for direct food contact in accordance with FDA and EU provisions 适合于食品直接接触的应用场合,符合 FDA 和 EU 相关法规 ? Highly effective defoamer/air release agent, particularly suitable for solvent-free high-solids and thick layer systems. 高效消泡剂/脱泡剂,尤其适合无溶剂/高固体份以及厚涂体系 ? Recommended for pigmented and non-pigmented systems 推荐用于色漆和清漆体系 ? Effective during production and further processing of the coatings 可在涂料的生产阶段及后续加工/施工过程中发挥作用 ? Has little to no effect on the surface properties or transparency 对表面性能和透明性影响很小甚至没有影响

BYK-1794 Properties 性能

Chemistry: 化学组成: Active substance: 活性物质: Hydrophobic particle: 憎水颗粒: VOC-free: 不含 VOC:

Mixture of foam destroying polymers
破泡聚合物混合物

100%

no


<1500 ppm (GC-Headspace; Greenability) (顶空气相法;绿色环保)

Silicone-free: 不含有机硅:

Yes


BYK-1794 Application Fields 应用领域

Architectural coatings 建筑涂料 BYK-1794

Wood and Furniture Coatings 木器和家 具涂料

Protective coatings 防腐涂料

Printing Inks 印刷油墨

Coil Coatings 卷材涂料

Ambient Curing Systems 室温固化 体系

Adhesives 胶粘剂

Recommended 推荐

Suitable 适用

? 100% 2-pack systems (epoxy, PUR and Polyaspartics) 100% 双组份体系(环氧、聚氨酯和聚天冬氨酸) ? High solid 1- and 2-pack systems 高固体份单组份和双组份体系

? 100% UV systems 100% UV 体系
? polyester/melamine coatings 聚酯/三聚氰胺涂料 ? 2-pack PUR adhesives 双组份聚氨酯胶粘剂

BYK-1794 Low Foam Formation in a 2-K Epoxy Coating for Flooring 减少双组份环氧地坪涂料中泡沫的形成

without defoamer 无消泡剂

1% BYK-1794

1% Competitor 竞争产品

BYK-1794 Efficient Defoaming of a 2-K PUR System 有效消除双组份聚氨酯体系的泡沫

0,2 % competitor 竞争产品

without defoamer 无消泡剂

0,2 % BYK-1794

BYK-1794 A Well-Balanced Defoamer 平衡性好的消泡剂

BYK-1794 is the perfect balance between defoaming efficiency and turbidity !
BYK-1794 在消泡性能和浑浊性方面取得了良好的平衡!

w/o defoamer 无消泡剂

0.5% BYK-1794

0.5% Competitor 竞争产品
Test system: epoxy floring

测试体系:环氧地坪

BYK-1794 Summary 总结

? 100 % solids 百分之百固体份 - Emission-free 零释放

- Meets AgBB standard as well as Swiss and French regulations
符合德国 AgBB 标准以及瑞士、法国的法规

- VOC-free 不含 VOC

? approved for food contact according to FDA and EU regulations
获准用于食品接触应用领域,符合 FDA 和 EU 法规

? highly effective in solvent-free, high solid an UV systems as well as thick layer systems
高效消泡剂,可用于无溶剂、高固体份、UV 体系以及厚涂体系

ANTI-TERRA?, BYK?, BYK?-DYNWET?, BYK?-SILCLEAN?, BYKANOL?, BYKETOL?, BYKOPLAST?, BYKUMEN?, DISPERBYK?, DISPERPLAST?, LACTIMON?, NANOBYK?, SILBYK? and VISCOBYK? are registered trademarks of BYK-Chemie. AQUACER?, AQUAFLOUR?, AQUAMAT?, CERACOL?, CERAFAK?, CERAFLOUR?, CERAMAT?, CERATIX? and MINERPOL? are registered trademarks of BYK-Cera. This information is given to the best of our knowledge. Because of the multitude of formulations, production, and application conditions, all the above mentioned statements have to be adjusted to the circumstances of the processor. No liabilities, including those for patent rights, can be derived from this fact for individual cases.


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