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中海壳牌石油化工有限公司 CNOOC and Shell Petrochemicals Company Limited

ERP ANNEX 11 SPILLAGE AND COUNTERMEASURES
DOCUMENT NO. PR-MFHS-0000-0031

DOCUMENT AUTHOR

DOCU

MENT REVIEWER ER Committee

DOCUMENT APPROVAL

REV

AMENDMENT DESCRIPTION

ISSUED DATE

MFHS

MF

01

Issued for discussion during 19-Oct-05 ERP Steering Committee

ERP Annex 11 Spillage and Counter-measures
CSPC –MS DOC NO. PR-MFHS-0000-0031 SUBMISSION DATE: 18-Oct-05 REV: 01 PAGE: 1 OF 9 FUNCTION: MFHS DOC. LEVEL:2

Level:2

中海壳牌石油化工有限公司 CNOOC and Shell Petrochemicals Company Limited Metadata: Unit No. Reference Document ALL Equipment No. ALL

PR-MFHS-0000-0023;PR-MFDM-0750-0003

Distribution list

Indicator MF MFO MFQ MFES MFEM MFLO MFSP MFUT MFPO MFPP MFLD MFHD MFEO MFDM MFTE MFHS

Name Bihou Jean-Louis Steve Johnson Colin Hunt Tiong Tung Yiw Alan Chua Dai Yu Joop van der Linden Fan Haichao Chew Yew Foo Lee CJ. Li Cai Daniel Pichette Ding Wanlin Anthony Woo Gerard DeNazelle Kong Hua

E/H Copy E E E E E E E E E E E E E E E E

ERP Annex 11 Spillage and Counter-measures
CSPC –MS DOC NO. PR-MFHS-0000-0031 SUBMISSION DATE: 18-Oct-05 REV: 01 PAGE: 2 OF 9 FUNCTION: MFHS DOC. LEVEL:2

Level:2

中海壳牌石油化工有限公司 CNOOC and Shell Petrochemicals Company Limited

TABLE OF CONTENTS
Page 1. PURPOSE ...................................................................................................................... 4

2. 2.1 2.2 3. 3.1 3.2 4.

SPILL CONTROL & COUNTERMEASURES ......................................................... 4 SPILLS ON LAND ........................................................................................................... 4 SPILLS TO SEA .............................................................................................................. 6 NOTIFICATIONS......................................................................................................... 7 AUTHORITIES ................................................................................................................ 7 CSPC MANAGEMENT.................................................................................................... 7 ON-SITE SUPPORT ..................................................................................................... 7

ATTACHMENT -

CSPC HAZMAT EQUIPMENT ........................................................ 9

ERP Annex 11 Spillage and Counter-measures
CSPC –MS DOC NO. PR-MFHS-0000-0031 SUBMISSION DATE: 18-Oct-05 REV: 01 PAGE: 3 OF 9 FUNCTION: MFHS DOC. LEVEL:2

Level:2

中海壳牌石油化工有限公司 CNOOC and Shell Petrochemicals Company Limited

1. PURPOSE To provides basic instructions for spill control and countermeasures.

2. SPILL CONTROL & COUNTERMEASURES Operators shall inspect their respective operating areas routinely. If a spill is detected, it shall be handled as quickly as possible according to procedures described below.

2.1

Spills On Land

A spill on a road surface may flow into Non-Contaminated System. In that case, containment and preventing spilled material from flowing into Non-Contaminated system is very important. A spill leading to the Accidentally Contaminated system (ADC) will flow into the Central Discharge Basin. The Central Discharge Basin is normally maintained at very low level for surges of rain fall. The outlets can be controlled. Use the following procedure if a chemical or hydrocarbon material is spilled on land or into the plant surface drainage system: a. Any person who discovers a spill will immediately notify the CSPC Fire Brigade Unit Shift Supervisor Utilities Shift Supervisor (re: Waste Water Treatment).

The Unit Shift Supervisor will decide whether it is necessary to contact the Unit Duty Manager. b. c. d. e. Instruct the Fire Brigade to approach the incident site from a safe route. Where special PPE is required in handling the clean up operation, this must be stated. Depending on the severity and material involved, the Unit operator will sound the unit alarm to alert the personnel in the unit. The unit operator will stop the source of spill (e.g. close valve, stop pump) promptly, if it is practicable and safe to do so. The Fire Brigade will assist the relevant unit operation team to contain the spill.

ERP Annex 11 Spillage and Counter-measures
CSPC –MS DOC NO. PR-MFHS-0000-0031 SUBMISSION DATE: 18-Oct-05 REV: 01 PAGE: 4 OF 9 FUNCTION: MFHS DOC. LEVEL:2

Level:2

中海壳牌石油化工有限公司 CNOOC and Shell Petrochemicals Company Limited f. If the response is beyond the capabilities of the CSPC resources or the Spill goes out of CSPC boundary, the relevant unit Shift Supervisor will activate the spill response contractors inform Unit communication person to activate Management Team (Emergency Control Center). the Emergency

Action Plan The following steps shall be taken at the incident site: a. The Fire Brigade will approach from a safe direction and create a control zone around the affected area to protect personnel. The affected area will be cordoned off to prevent unauthorised personnel from entering the spill area. All personnel who are involved in the spill mitigation will wear the appropriate PPE including protective suits, boots, gloves and full face shields. SCBA shall also be worn if necessary. The Fire Brigade has Level A and Level B protective equipment and tools to fight the corrosive and hazardous chemical spills. Contain the spill with sand bags or other barriers d absorbent pads are stored at relevant unit locations sand bags are stored at locations of expected use other additional spill-containment materials are kept by the CSPC Fire Brigade transfer or offloading (e.g. tank-car) shut off the leaking source if it can be safely done (e.g. leaking valve and leakage rate is low)

b.

c

Take measures to stop or minimize the spill including: -

e f

Operations will neutralise the spillage if necessary (e.g. acids spills may be neutralised with soda ash) Call the Spillage Response contractor, chemical vendor or Waste Management contractor to recover the contained spill. The contractor will collect the spilled liquid into containers using diaphragm pumps or vacuum trucks. Send the recovered spillage to CSPC Waste Treatment or incinerator if possible, otherwise send for treatment by approved third parties Waste management Contractor will thoroughly clean up of the surrounding area: clean up the last traces of spillage using an absorbent material. sometimes it may be possible to wash down the affected area with water, after the chemical has been removed.

g h

ERP Annex 11 Spillage and Counter-measures
CSPC –MS DOC NO. PR-MFHS-0000-0031 SUBMISSION DATE: 18-Oct-05 REV: 01 PAGE: 5 OF 9 FUNCTION: MFHS DOC. LEVEL:2

Level:2

中海壳牌石油化工有限公司 CNOOC and Shell Petrochemicals Company Limited i Handle the contaminated PPE, equipment, offloading hoses and absorbent materials in accordance with CSPC hazardous Waste Management Procedures.

2.2

Spills To Sea

Use the following procedure if a chemical or hydrocarbon material is spilled into Daya Bay: a. Any person who discovers a spill from the marine facilities will immediately notify the CSPC Fire Brigade and the CSPC MFDM3 (TankFarm & Jetty Shift Supervisor or TJ Shift Supervisor). The TJ Shift Supervisor will activate emergency shutdown procedures if loading/unloading operations are in progress. The TJ Shift Supervisor will report to Huizhou MSA and activate the Marine Spillage Response contractors. The TJ Shift Supervisor will inform the MFDM Duty Manager. The MFDM Duty Manager will decide whether to activate the CSPC Emergency Management Team to support the response activities from the Emergency Control Centre. If the Emergency Management Team is activated, the Site Duty manager (as Incident Commander) will decide whether it is necessary to notify CSPC management and outside agencies.

b. c. d. e.

f.

Action Plan a. Spills into Daya Bay will most likely take place at the berths. The CSPC Marine Emergency Procedure – Oil/Chemical Spill contains detailed steps to follow in the event of a jetty-related spill. Spills via CSPC Waste Water Discharge pipeline (PLUTO) are not likely to occur If a major spill has taken place, the marine response network will be activated. The TJ Shift Supervisor will coordinate spill containment and recovery operations, until he is relieved by his superior or the MFDM Duty Manager. One or more of the recovery systems below will be used: EQUIPMENT AND USE Land Spill Response contractor or Waste Management Contractor will be activated to recover the spillage.

b.

LOCATION On land

ERP Annex 11 Spillage and Counter-measures
CSPC –MS DOC NO. PR-MFHS-0000-0031 SUBMISSION DATE: 18-Oct-05 REV: 01 PAGE: 6 OF 9 FUNCTION: MFHS DOC. LEVEL:2

Level:2

中海壳牌石油化工有限公司 CNOOC and Shell Petrochemicals Company Limited Sea Marine Spill Response contractor (listed in the Communication List) will be activated to contain and recover the spill. Marine Spill Response contractor will apply sorbents or boom to remove spillage. Marine Spill Response contractor will collect the spillage.

Spillage caught around jetty Along the shore or contained by boom

3. 3.1

NOTIFICATIONS Authorities

MFHS has the responsibility to ensure that the relevant authorities are timely notified, especially the Environmental Protection Bureau. Timing for reporting to Work Safety Supervision Bureau and Fire-fighting Bureau depends on the number of fatalities and extend of damage. Details are provided in document PR-MFHS-0000-0026 Incident Classification & Reporting Procedure MFDM has the responsibily to ensure that the Marine Safety Administration are timely notified. 3.2 CSPC Management The Incident Commander has the responsibilityy to ensure that the CSPC Management is timely notified

4. ON-SITE SUPPORT During the Commissioning period, Panyu LuYou has been contracted to provide spillage recovery services. Equipent available on-site: ? ? ? One 18-Ton Tanker Truck One diaphragm pump Ten Rubber Containers, each one-ton capacity

Contact Persons : BSF Commissioning ? Shi Weijun 13927370750

ERP Annex 11 Spillage and Counter-measures
CSPC –MS DOC NO. PR-MFHS-0000-0031 SUBMISSION DATE: 18-Oct-05 REV: 01 PAGE: 7 OF 9 FUNCTION: MFHS DOC. LEVEL:2

Level:2

中海壳牌石油化工有限公司 CNOOC and Shell Petrochemicals Company Limited ?
? ? ? ?

Zhang Yu

13927370782

Contact Persons : Panyu LuYou
Xun Jianhong 13790786663/13928799888 Song Yuxiong 13790786665 Liu Bing 13825497859 Zheng Shaopeng 13433577392

?

or inform Daya Bay office of Luyou company :5563391

ERP Annex 11 Spillage and Counter-measures
CSPC –MS DOC NO. PR-MFHS-0000-0031 SUBMISSION DATE: 18-Oct-05 REV: 01 PAGE: 8 OF 9 FUNCTION: MFHS DOC. LEVEL:2

Level:2

中海壳牌石油化工有限公司 CNOOC and Shell Petrochemicals Company Limited ATTACHMENT CSPC HAZMAT EQUIPMENT Quantity
25 prs 20 prs 15 prs 200 ors 4 prs 4 prs 25 prs 1 set 1 set 2 sets 2 sets

Description
Hazmat Boots Hazmat glove Level A chemical suit Disposable chemical suit EO Suit TEAL Suit Ice vest Ice Chest – 200 litre Drum-plugging kit Instant patch putty Chemical tape
inch

Kept by
Fire Brigade Fire Brigade Fire Brigade Fire Brigade EOEG PP Fire Brigade Fire Brigade Fire Brigade Fire Brigade Fire Brigade Fire Brigade Fire Brigade Fire Brigade Fire Brigade MFUT MFUT

Kept in
Fire Station Fire Station Fire Station Fire Station CC1 CC2 Fire Station Fire Station Fire Station Fire Station Fire Station Fire Station Fire Station Fire Station Fire Station HazchemYard

Propylene rope – quarter- 50m Propylene rope – half-inch Decontamination kit Level A test kit Empty Containers Diaphragm Pumps 50m 1 set 1 set

ERP Annex 11 Spillage and Counter-measures
CSPC –MS DOC NO. PR-MFHS-0000-0031 SUBMISSION DATE: 18-Oct-05 REV: 01 PAGE: 9 OF 9 FUNCTION: MFHS DOC. LEVEL:2

Level:2


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